第四章 热力学规定值
- \(\lim\limits_{T\to{0}}T(\frac{\partial{\Delta{G}}}{\partial{T}})_p=0\)
- \(\lim\limits_{T\to0}S=0\) 绝对零度&完美晶体物质
- 不能用有限手续将任何一个体系的温度降低到绝对零度（热力学第三定律）
- \(\lim\limits_{T\to0}C_{V}=0\) 绝对零度&完美晶体物质
- \(\lim\limits_{T\to0}C_{p}=0\) 绝对零度&完美晶体物质
- \(\lim\limits_{T\to0}(\frac{\partial{S}}{\partial{p}})_T=\lim\limits_{T\to0}-(\frac{\partial{V}}{\partial{T}})_p=0\) 绝对零度&完美晶体物质
- \(\lim\limits_{T\to0}(\frac{\partial{S}}{\partial{V}})_T=\lim\limits_{T\to0}(\frac{\partial{p}}{\partial{T}})_V=0\) 绝对零度&完美晶体物质
- \(\Delta_rG_m^\Theta(T)=\sum\limits_B\nu_BG_m^\Theta(B,T)\)
- \(\Delta_rS_m^\Theta(T)=\sum\limits_B\nu_BS_m^\Theta(B,T)\)
